Nickel(II) and Iron(II) coordination compounds with octahydrotriborate(1–) anion [ML 3 ]{B 3 H 8 } 2  (M = Fe 2+ , Ni 2+ ; L = bipy, phen)

N. A. Selivanov; A. Yu. Bykov; M. S. Grigor’ev; K. Yu. Zhizhin; N. T. Kuznetsov

doi:10.1134/S0012500816030034

Nickel(II) and Iron(II) coordination compounds with octahydrotriborate(1–) anion [ML₃]{B₃H₈}₂ (M = Fe²⁺, Ni²⁺; L = bipy, phen)

Authors: Selivanov N.A.¹, Bykov A.Y.¹, Grigor’ev M.S.², Zhizhin K.Y.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry
2. Frumkin Institute of Physical Chemistry and Electrochemistry
Issue: Vol 467, No 1 (2016)
Pages: 64-68
Section: Chemistry
URL: https://journal-vniispk.ru/0012-5008/article/view/153587
DOI: https://doi.org/10.1134/S0012500816030034
ID: 153587

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Abstract

Methods of synthesis have been developed for new types of promising precursors of metal borides, coordination compounds [ML₃]B{₃H₈{₂ (M = Fe²⁺, Ni²⁺; L = bipy, phen), using modified procedures of synthesis of octahydrotriborate anion. Compounds [Ni(bipy)₃]B{₃H₈}₂, [Ni (phen)₃]B{₃H₈}₂ and [Fe(phen)₃]B{₃H₈}₂ were prepared and characterized by single-crystal X-ray diffraction.