Enviar artigo por via de e-mail Synthesis and Testing of Abscisic Acid with Predominant Replacement of Protium Atoms by Tritium in the Cyclohexene Moiety
- Autores: Shevchenko V.P.1, Nagaev I.Y.1, Shaposhnikov A.I.2, Shevchenko K.V.1, Belimov A.A.2, Batasheva S.N.3, Gogoleva N.E.3,4, Gogolev Y.V.3,4, Myasoedov N.F.1
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Afiliações:
- Institute of Molecular Genetics, Russian Academy of Sciences
- All-Russian Research Institute for Agricultural Microbiology
- Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center, Russian Academy of Sciences
- Kazan (Volga Region) Federal University
- Edição: Volume 483, Nº 1 (2018)
- Páginas: 268-271
- Seção: Chemistry
- URL: https://journal-vniispk.ru/0012-5008/article/view/154138
- DOI: https://doi.org/10.1134/S0012500818110113
- ID: 154138
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Resumo
A procedure for tritiation of predominantly the cyclohexene moiety of abscisic acid was developed. Tritium was introduced by isotope exchange reaction with 100% tritiated water at 220°C in the presence of diisopropylethylamine. The yield of abscisic acid was 50%, and the specific activity was 30.5 Ci/mmol. The labeled product was tested. It was shown that tritiated abscisic acid synthesized by the proposed method did not differ from the unlabeled precursor and could be used for biological assays.
Sobre autores
V. Shevchenko
Institute of Molecular Genetics, Russian Academyof Sciences
Autor responsável pela correspondência
Email: nagaev@img.ras.ru
Rússia, Moscow, 123182
I. Nagaev
Institute of Molecular Genetics, Russian Academyof Sciences
Email: nagaev@img.ras.ru
Rússia, Moscow, 123182
A. Shaposhnikov
All-Russian Research Institute for Agricultural Microbiology
Email: nagaev@img.ras.ru
Rússia, St. Petersburg, 196608
K. Shevchenko
Institute of Molecular Genetics, Russian Academyof Sciences
Email: nagaev@img.ras.ru
Rússia, Moscow, 123182
A. Belimov
All-Russian Research Institute for Agricultural Microbiology
Email: nagaev@img.ras.ru
Rússia, St. Petersburg, 196608
S. Batasheva
Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center, Russian Academy of Sciences
Email: nagaev@img.ras.ru
Rússia, Kazan, 420088
N. Gogoleva
Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center, Russian Academy of Sciences; Kazan (Volga Region) Federal University
Email: nagaev@img.ras.ru
Rússia, Kazan, 420088; Kazan,, 420008
Yu. Gogolev
Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center, Russian Academy of Sciences; Kazan (Volga Region) Federal University
Email: nagaev@img.ras.ru
Rússia, Kazan, 420088; Kazan,, 420008
N. Myasoedov
Institute of Molecular Genetics, Russian Academyof Sciences
Email: nagaev@img.ras.ru
Rússia, Moscow, 123182
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