Отправить статью по E-mail Chemistry of the CARBEX process: Identification of absorption bands of the ligands in the electronic spectra of aqueous solutions of Na4[UO2(O2)CO3)2]
- Авторы: Boyarintsev A.V.1, Stepanov S.I.1, Chekhlov A.A.1, Chekmarev A.M.1, Tsivadze A.Y.2
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Учреждения:
- Mendeleev University of Chemical Technology of Russia
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Выпуск: Том 469, № 2 (2016)
- Страницы: 227-232
- Раздел: Chemistry
- URL: https://journal-vniispk.ru/0012-5008/article/view/153737
- DOI: https://doi.org/10.1134/S0012500816080024
- ID: 153737
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Аннотация
On the basis of consideration of dissociation, hydration, association, and ligand exchange, the assignment of absorption bands in the electronic spectra of aqueous solutions of the Na4[UO2(O2)CO3)2] complex has been performed. It has been demonstrated that the absorption in the range 190–400 nm is caused by the oxygen atoms of the O22- and CO32- groups and hydration water molecules of dissociated and neutral complex species Na3[UO2(O2)(CO3)2]–, Na2[UO2(O2)(CO3)2]2–, and Na4[UO2(O2)(CO3)2].
Об авторах
A. Boyarintsev
Mendeleev University of Chemical Technology of Russia
Email: chao_step@mail.ru
Россия, Miusskaya pl. 9, Moscow, 125047
S. Stepanov
Mendeleev University of Chemical Technology of Russia
Автор, ответственный за переписку.
Email: chao_step@mail.ru
Россия, Miusskaya pl. 9, Moscow, 125047
A. Chekhlov
Mendeleev University of Chemical Technology of Russia
Email: chao_step@mail.ru
Россия, Miusskaya pl. 9, Moscow, 125047
A. Chekmarev
Mendeleev University of Chemical Technology of Russia
Email: chao_step@mail.ru
Россия, Miusskaya pl. 9, Moscow, 125047
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: chao_step@mail.ru
Россия, Leninskii pr. 31, Moscow, 119071
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