Chemistry of the CARBOFTOREX process. Identification of the absorption bands of the ligands in the electronic spectra of aqueous solutions of uranyl fluoride


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The electronic absorption bands of aqueous solutions of the [UO2F2(H2O)n] complex were assigned taking into account dissociation, hydration, association, and ligand exchange. The absorption in the range of 190–400 nm was found to be related to the formation of cationic, neutral, and anionic complex species, [UO2F2(H2O)n].

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S. Stepanov

Mendeleev University of Chemical Technology; Frumkin Institute of Physical Chemistry and Electrochemistry

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Email: chao_step@mail.ru
俄罗斯联邦, Moscow, 125190; Moscow, 117071

A. Boyarintsev

Mendeleev University of Chemical Technology; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: chao_step@mail.ru
俄罗斯联邦, Moscow, 125190; Moscow, 117071

A. Chekhlov

Mendeleev University of Chemical Technology; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: chao_step@mail.ru
俄罗斯联邦, Moscow, 125190; Moscow, 117071

A. Chekmarev

Mendeleev University of Chemical Technology; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: chao_step@mail.ru
俄罗斯联邦, Moscow, 125190; Moscow, 117071

A. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: chao_step@mail.ru
俄罗斯联邦, Moscow, 117071

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