New Photochromic Spiropyrans with ortho-Hydroxyaldimine Substituent


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A series of new spiropyrans of indoline series with ortho-hydroxyaldimine substituent has been synthesized, their structure and photochromic properties have been studied. The structure of the obtained compounds was confirmed by the data of 1H NMR and IR spectroscopy and elemental analysis. Photochromic properties of the prepared compounds have been studied. The introduction of ortho-hydroxy group into aldimine fragment of molecule (in the 6 position of the 2H-chromene fragment) has increased the lifetime of merocyanine isomer by 40 times as compared with amino-substituted spiropyran.

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O. Komissarova

Research Institute of Physical and Organic Chemistry

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Email: komissarovaoxana@mail.ru
俄罗斯联邦, Rostov-on-Don, 344090

B. Luk’yanov

Research Institute of Physical and Organic Chemistry; Don State Technical University

Email: komissarovaoxana@mail.ru
俄罗斯联邦, Rostov-on-Don, 344090; Rostov-on-Don, 344007

M. Luk’yanova

Research Institute of Physical and Organic Chemistry

Email: komissarovaoxana@mail.ru
俄罗斯联邦, Rostov-on-Don, 344090

N. Makarova

Research Institute of Physical and Organic Chemistry

Email: komissarovaoxana@mail.ru
俄罗斯联邦, Rostov-on-Don, 344090

I. Rostovtseva

Research Institute of Physical and Organic Chemistry

Email: komissarovaoxana@mail.ru
俄罗斯联邦, Rostov-on-Don, 344090

I. Ozhogin

Research Institute of Physical and Organic Chemistry

Email: komissarovaoxana@mail.ru
俄罗斯联邦, Rostov-on-Don, 344090

M. Korobov

Research Institute of Physical and Organic Chemistry

Email: komissarovaoxana@mail.ru
俄罗斯联邦, Rostov-on-Don, 344090

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