Email this article Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine
- Authors: Shakirova O.G.1, Lavrenova L.G.2,3, Kuratieva N.V.2,3, Bogomyakov A.S.3,4, Sheludyakova L.A.2,3, Mosalkova A.P.5, Grigoriev Y.V.5
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Affiliations:
- Komsomolsk-on-Amur State Technical University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- International Tomography Center, Siberian Branch
- Research Institute for Physical Chemical Problems of the Belarusian State University
- Issue: Vol 58, No 5 (2017)
- Pages: 919-925
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161490
- DOI: https://doi.org/10.1134/S0022476617050092
- ID: 161490
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Abstract
Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.
About the authors
O. G. Shakirova
Komsomolsk-on-Amur State Technical University
Email: ludm@niic.nsc.ru
Russian Federation, Komsomolsk-on-Amur
L. G. Lavrenova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Author for correspondence.
Email: ludm@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
N. V. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: ludm@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
A. S. Bogomyakov
Novosibirsk National Research State University; International Tomography Center, Siberian Branch
Email: ludm@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
L. A. Sheludyakova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: ludm@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
A. P. Mosalkova
Research Institute for Physical Chemical Problems of the Belarusian State University
Email: ludm@niic.nsc.ru
Belarus, Minsk
Yu. V. Grigoriev
Research Institute for Physical Chemical Problems of the Belarusian State University
Email: ludm@niic.nsc.ru
Belarus, Minsk
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