Synthesis and Structural Characterization of a Zinc Cooridination Polymer with bis(4-(1 H -Imidazol-1-Yl)Phenyl)Methanone and 4-Nitrophthalate

X. Yang; G.-F. Wang; L. Yang

doi:10.1134/S0022476618070235

Synthesis and Structural Characterization of a Zinc Cooridination Polymer with bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone and 4-Nitrophthalate

Authors: Yang X.¹, Wang G.¹, Yang L.²
Affiliations:
1. Department of Applied Chemistry
2. College English Department
Issue: Vol 59, No 7 (2018)
Pages: 1684-1687
Section: Article
URL: https://journal-vniispk.ru/0022-4766/article/view/161780
DOI: https://doi.org/10.1134/S0022476618070235
ID: 161780

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Abstract

A zinc coordination polymer with the formula {[Zn(npa)(L¹)]·2H₂O}_n (1) (L¹ = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H₂npa = 4-nitrophthalic acid) is synthesized and characterized by IR, elemental analysis, and single crystal X-ray diffraction. The Zn²⁺ ion has a distorted tetrahedral environment with two O atoms from two npa ligands and two N atoms from two L¹ ligands. Each L¹ acts as a bridging ligand to link the neighboring [Zn(npa)]₂ dimers to form a 1D ladder.