Thermoinduced Structural Transformations of [Fe(hfac) 2 (THF) 2 ]

G. V. Romanenko; S. V. Fokin; D. P. Pishchur; A. S. Bogomyakov; V. I. Ovcharenko

doi:10.1134/S0022476619100081

Thermoinduced Structural Transformations of [Fe(hfac)₂(THF)₂]

Authors: Romanenko G.V.¹, Fokin S.V.¹, Pishchur D.P.², Bogomyakov A.S.¹, Ovcharenko V.I.¹
Affiliations:
1. International Tomography Center, Siberian Branch
2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Issue: Vol 60, No 10 (2019)
Pages: 1630-1634
Section: Article
URL: https://journal-vniispk.ru/0022-4766/article/view/162204
DOI: https://doi.org/10.1134/S0022476619100081
ID: 162204

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Abstract

It is found that on cooling from 295 K to 100 K, [Fe(hfac)₂(THF)₂] crystals undergo reversible phase transitions during which their symmetry changes and one of the unit cell parameters doubles.