Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids: The Effect of Acidity on the Catalytic Activity
- Authors: Badmaev S.D.1,2, Smorygina A.S.2, Paukshtis E.A.1,2, Belyaev V.D.1, Sobyanin V.A.1, Parmon V.N.1
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Affiliations:
- Boreskov Institute of Catalysis, Siberian Branch
- Novosibirsk State University
- Issue: Vol 59, No 1 (2018)
- Pages: 99-103
- Section: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/163598
- DOI: https://doi.org/10.1134/S0023158418010020
- ID: 163598
Cite item
Abstract
The gas-phase carbonylation reaction of dimethoxymethane (DMM) to methyl methoxyacetate on different solid acids was studied. It was established that this reaction was accompanied by the occurrence of a side reaction of DMM disproportionation into dimethyl ether and methyl formate. It was shown that the activity of solid acids in both of the reactions depends on the strength of Brønsted acid sites according to an equation like the Brønsted–Evans–Polanyi–Semenov correlations.
About the authors
S. D. Badmaev
Boreskov Institute of Catalysis, Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: sukhe@catalysis.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
A. S. Smorygina
Novosibirsk State University
Email: sukhe@catalysis.ru
Russian Federation, Novosibirsk, 630090
E. A. Paukshtis
Boreskov Institute of Catalysis, Siberian Branch; Novosibirsk State University
Email: sukhe@catalysis.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
V. D. Belyaev
Boreskov Institute of Catalysis, Siberian Branch
Email: sukhe@catalysis.ru
Russian Federation, Novosibirsk, 630090
V. A. Sobyanin
Boreskov Institute of Catalysis, Siberian Branch
Email: sukhe@catalysis.ru
Russian Federation, Novosibirsk, 630090
V. N. Parmon
Boreskov Institute of Catalysis, Siberian Branch
Email: sukhe@catalysis.ru
Russian Federation, Novosibirsk, 630090
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