Email this article The Kinetics of the Reaction of Carbon Dioxide with Propylene Oxide Catalyzed by a Chromium–Salen Complex
- Authors: Chukanova O.M.1, Belov G.P.1
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Affiliations:
- Institute of Problems of Chemical Physics
- Issue: Vol 59, No 3 (2018)
- Pages: 262-266
- Section: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/163721
- DOI: https://doi.org/10.1134/S0023158418030059
- ID: 163721
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Abstract
The kinetics of the reaction of CO2 with propylene oxide utilizing a salenCrCl/PPNCl active catalytic system is studied with varying reaction conditions (temperature, pressure, and cocatalyst/catalyst ratio). The reaction proceeds selectively to form cyclic propylene carbonate (PC) at [PPNCl]/[salenCrCl] ratios above two. The value of the effective activation energy of PC formation is found.
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About the authors
O. M. Chukanova
Institute of Problems of Chemical Physics
Author for correspondence.
Email: olchukan@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
G. P. Belov
Institute of Problems of Chemical Physics
Email: olchukan@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
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