Effect of the State of a Surface Layer on the Properties of Pd–P Catalysts in the Hydrogenation of Alkylanthraquinones
- Authors: Belykh L.B.1, Sterenchuk T.P.1, Skripov N.I.1, Akimov V.V.2, Tauson V.L.2, Romanchenko A.S.3, Gvozdovskaya K.L.1, Sanzhieva S.B.1, Shmidt F.K.1
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Affiliations:
- Irkutsk State University
- Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences
- Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences
- Issue: Vol 60, No 6 (2019)
- Pages: 808-817
- Section: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/164311
- DOI: https://doi.org/10.1134/S0023158419060028
- ID: 164311
Cite item
Abstract
X-ray photoelectron spectroscopy (XPS) was used to study the state of the surface layer of a Pd–P catalyst, which exhibits high selectivity in the hydrogenation of 2-ethyl-9,10-anthraquinone. The preparation of the catalyst from Pd(acac)2 and white phosphorus in hydrogen in a toluene–1-octanol solution led to the formation of Pd–P nanoparticles whose surface was enriched in electron-deficient palladium, apparently, as a constituent of an amorphized 2D layer based on a solid solution of Pd and P. Octyl esters of phosphoric acids, adsorbed on the surface, acted as stabilizers. A relationship between the properties of the Pd–P catalyst in the hydrogenation of 2-ethyl-9,10-anthraquinone and the state of the surface layer was considered.
About the authors
L. B. Belykh
Irkutsk State University
Author for correspondence.
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003
T. P. Sterenchuk
Irkutsk State University
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003
N. I. Skripov
Irkutsk State University
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003
V. V. Akimov
Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664033
V. L. Tauson
Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664033
A. S. Romanchenko
Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch,Russian Academy of Sciences
Email: belykh@chem.isu.ru
Russian Federation, Krasnoyarsk, 660036
K. L. Gvozdovskaya
Irkutsk State University
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003
S. B. Sanzhieva
Irkutsk State University
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003
F. K. Shmidt
Irkutsk State University
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003
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