Effect of the State of a Surface Layer on the Properties of Pd–P Catalysts in the Hydrogenation of Alkylanthraquinones


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Abstract

X-ray photoelectron spectroscopy (XPS) was used to study the state of the surface layer of a Pd–P catalyst, which exhibits high selectivity in the hydrogenation of 2-ethyl-9,10-anthraquinone. The preparation of the catalyst from Pd(acac)2 and white phosphorus in hydrogen in a toluene–1-octanol solution led to the formation of Pd–P nanoparticles whose surface was enriched in electron-deficient palladium, apparently, as a constituent of an amorphized 2D layer based on a solid solution of Pd and P. Octyl esters of phosphoric acids, adsorbed on the surface, acted as stabilizers. A relationship between the properties of the Pd–P catalyst in the hydrogenation of 2-ethyl-9,10-anthraquinone and the state of the surface layer was considered.

About the authors

L. B. Belykh

Irkutsk State University

Author for correspondence.
Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003

T. P. Sterenchuk

Irkutsk State University

Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003

N. I. Skripov

Irkutsk State University

Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003

V. V. Akimov

Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences

Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664033

V. L. Tauson

Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences

Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664033

A. S. Romanchenko

Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch,
Russian Academy of Sciences

Email: belykh@chem.isu.ru
Russian Federation, Krasnoyarsk, 660036

K. L. Gvozdovskaya

Irkutsk State University

Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003

S. B. Sanzhieva

Irkutsk State University

Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003

F. K. Shmidt

Irkutsk State University

Email: belykh@chem.isu.ru
Russian Federation, Irkutsk, 664003

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