


Vol 59, No 11-12 (2016)
- Year: 2016
- Articles: 39
- URL: https://journal-vniispk.ru/0026-0894/issue/view/14739
Article
Status and Prospects of Ferroalloys Production in the Russian Federation
Abstract
Data are presented on the production and consumption of ferroalloys in the Russian Federation from 1994 to 2014. The quantities of the main ferroalloys that were made during this period are compared to the volume of steel production, and a comparison is also made between the structure of ferroalloys production in Russia and abroad. Data on the import, export, and apparent consumption of ferroalloys ate also reported. It is noted that Russia needs to expand its raw-materials base in order to make the main ferroalloys: manganese-, chromium-, and silicon-based ferroalloys. Such expansion is necessary to ensure that Russian companies can compete in the international market and that Russia is not threatened economically. These goals can be accomplished only with the support of the government.



Computer Study of the Effect of Tooling Geometry on Deformation Parameters in the Plastic Shaping of Aluminum Wire Rod by Multi-ECAP-Conform
Abstract
Results are presented from a computer study of a promising method of high-rate plastic deformation – Multi-ECAP-Conform (M-ECAP-C) – for obtaining long ultrafine-grained semifinished products (wire rods) of aluminum alloy EN-AW 6101 in a single pressing cycle. It is shown that the distribution of cumulative strain in a semifinished product can be controlled by changing the geometry of the tool. The study examined three geometric variants for the outlet section of the pressing channel and used the results to develop an efficient new channel geometry for pressing by the M-ECAP-C method. The new channel shape makes the strain state of semifinished products more uniform during the stage of stable flow of the material, lowers the pressing forces, and reduces the tensile stresses in the deformation zone.



Accounting for the Technological History of the Formation of a Part in Strength Calculations. Part 2*
Abstract
Strength calculations are performed for a new part with allowance for the forming operations used to make it. The process of accounting for the technological history of the part in such calculations is illustrated by examining the strength design of an equipment component consisting of several parts made by different forming methods.



Prospects for the Use of Drum-Type Units to Recycle Metallurgical Slags
Abstract
This article examines one of several approaches currently being taken to the recycling of metallurgical slag in the liquid state inside drum-type units. Technological and design features of the units are discussed. The recycling units make it possible to obtain different types of products from slag melts. A new design of an experimental rotor-type unit is also described.



Liquid-Phase Reduction of Steelmaking Wastes
Abstract
Results are presented from a study of the liquid-phase reduction of the pre-concentrated metallic component of discarded steelmaking slag. The cost-effectiveness of this technology is evaluated and it is shown that it is best used as the second stage of a two-stage slag recycling operation.



Method of Monitoring the Profile of a Blast Furnace and the Results of its Use
Abstract
A new method is proposed for monitoring the internal profile of blast furnaces. The method is based on the use of a compact measurement unit comprised of a laser rangefinder and a digital goniometer. Results are reported from the use of the method to evaluate the actual profile of the shaft of a blast furnace while it was banked. The technology is shown to have promise when used in combination with thermographic monitoring of the technical condition of the top of the shaft and monitoring of heat losses in the cooling system.



Effect of Oxides of Magnesium and Manganese and the Basicity of the Iron-Ore-Bearing Materials on the Ability of the Smelting Products to Filter Through the Coke Column in Blast Furnaces
Abstract
One way of increasing the smelting rate in a blast furnace is to increase the gas permeability of the lower part of the stock. Gas permeability in this zone and the smoothness of the furnace’s operation depend on the ability of the intermediate slag to filter through the coke column. A method of studying filterability has been developed and introduced, the method making it possible to reliably assess the behavior of the iron-orebearing materials in a blast furnace at high temperatures. It was established by laboratory studies and confirmed by factory tests that the filterability of molten blast-furnace slag is affected by the presence of the oxides MgO, MnO, and CaO, which are added to charge that is used to make sinter. The magnitude of this effect depends on the composition of the minerals that contain these oxides.



Analysis of the Kinetics of the Solidification of Steel Forging Ingots of Different Configurations. Part I. Results from Cold Modeling
Abstract
Cold modeling is performed on transparent models to examine the effect of the configuration of forging ingots on the kinetics of their solidification. Aspects of the changes in the vertical and horizontal solidification rates across the ingots are studied in the investigation.



Modification of Steel and Alloys with Rare-Earth Elements. Part 1
Abstract
Physical and physicochemical properties are considered for rare-earth elements (metals) and their reaction with oxygen, sulfur, and nonferrous metal admixtures during steel production. Introduction of REMs in optimum amounts makes it possible to modify nonmetallic inclusions both in a liquid condition and during steel crystallization, to refine cast workpiece structure due to inoculation action, and to improve physicomechanical and operating properties of a broad range of steels and alloys. Melt stirring is necessary in order to improve steel purity with respect to nonmetallic inclusions during REM introduction and subsequent steel treatment.



“Bainitic Refinement” of Machine Steels Microalloyed with Vanadium and Nitrogen
Abstract
The effect of microalloying additions of N, V, Ti, Al, and Nb on structure formation and properties of medium-carbon steels alloyed mainly with chromium (30Kh2AF–40Kh2FABT type) is considered. Steel microalloying makes it possible to provide marked austenite structure refinement due to grain growth limitation by (Ti, V)N particles, retardation of austenite recrystallization and grain growth during stamping by Nb(C, N) particles (and Nb in solid solution), which leads to the formation of a fine final steel structure, as a result of which there is improvement of both strength properties and impact strength. Steel of the class in question may be produced by economic controlled stamping technology with cooling from rolling heating and subsequent tempering instead of heat treatment with quenching and separate heating and tempering. As a result, a unique set of properties is achieved: mechanical properties, brittle failure resistance, corrosion resistance, seismic resistance, fire resistance of long rolled product, building structure components, engineering components, oil recovery equipment, etc.



Effect of Technology for Modification with Calcium and Ree on Pipe Steel Nonmetallic Inclusion Morphology and Production Properties
Abstract
The effect of pipe billet production technology and of the order of introducing rare-earth elements and calcium on nonmetallic inclusion composition and morphology is studied. The correlation of inclusion morphology with corrosion resistance and casting suitability for steel in a CBCM is evaluated.



Effect of Mn, Al, Ni, and C Content on the Equilibrium Phase Composition of Alloys Based on the Fe–Mn–Al–Ni–C System
Abstract
A Thermo-Calc program is used to calculate isothermal and polythermal sections of diagrams and phase composition for alloys of the Fe–Mn–Al, Fe–Mn–Al–Ni, and Fe–Mn–Al–Ni–C systems. Phase diagrams are used to study the effect of nickel, aluminum, manganese, and carbon on the equilibrium structure of alloys of the Fe–Mn–Al–Ni–C system. Concentration ranges are determined for existence of single-phase γ-alloys in the range 1000–1200°C. It is established that achievement of a considerable aluminum content (10%) and existence of increased specific strength for austenitic alloys of the Fe–Mn–Al–Ni–C system containing not less than 5% Ni is possible with a manganese content of not less than 20% and carbon not less than 1.4%.



Development of Slag-Forming Mixture for Steel-Pouring Ladle and its Application Technology During Production of Steels with High Aluminum and Sulfur Content
Abstract
Flotation and assimilation of nonmetallic inclusions from metal slag in steel-pouring ladles and tundishes during pouring steels with increased aluminum and sulfur content are considered. The authors study the formation of nonmetallic inclusions in a steel-pouring ladle during steel extra-furnace treatment, the process of submerged nozzle clogging during continuous casting, the change in slag composition in a tundish, and development of an assimilation mixture composition for a steel-pouring ladle. Laboratory studies are made of the physicochemical properties of a developed SFM. It is established that use of the new SFM makes it possible to improve nonmetallic inclusion assimilation in a steel-pouring ladle and does not lead to a marked change in slag chemical composition and physical properties in a tundish. As a result of this, there is less steel contamination with nonmetallic inclusions and a reduction in submerged nozzle clogging.



Mechanisms for Improving Chemical and Structural Homogeneity of Hot-Rolled Product for Objects Prepared by Hot Stamping
Abstract
Redistribution of components forming the structure and properties during hot rolling of microalloyed steels, similar in chemical composition to hardened steels during hot stamping, of an industrial melt containing carbon from 0.098 to 0.219%, is studied in detail. It is established that a key production parameter controlling the intensity of occurrence of these processes is the temperature at the start of rolling in the finishing group of stands, i.e., T6. An increase in T6 leads to significant enrichment with respect to carbon content, and a finer structure due to the formation of niobium carbonitride precipitates in surface layers compared with the rolled product axial zone. An increase in carbon content and a reduction in the concentration of niobium and other microalloying components within steel reduces the intensity of development of these processes. It has been shown by experiment that significant metal chemical and structural inhomogeneity forming in the continuous billet casting stage may be avoided or significantly reduced during hot rolling on the basis of controlling excess phase precipitation. This leads to a marked increase in the level of production and service properties of both hot-rolled product and metal objects prepared from it by hot stamping.



Study of the Effect of Chemical Composition and Heat Treatment on Corrosion Resistance Indices for Martensitic Class Stainless Steels Alloyed with Nitrogen
Abstract
Corrosion tests are performed on developed chromium corrosion-resistant steels alloyed with nitrogen. A set of tests shows that depending on chemical composition and production parameters the corrosion resistance indices for steels of one class may differ by an order of magnitude. Revelation of a dependence makes it possible to conclude that an increase within steel of nitrogen and molybdenum content combined with quenching and low-temperature tempering at 400°C makes it possible to prepare steel with good pitting corrosion resistance in aqueous media, particularly, under sea water conditions.



Evaluation of the Possibility of Retarding Steel Recrystallization During Hot Rolling with Precipitation of Manganese Sulfide Particles
Abstract
The article is devoted to finding new production methods making it possible to prepare rolled product of carbon or low-alloy steels with a fine-grained structure, and this means greater strength with limitation or exclusion of expensive alloying with niobium. The possibility is considered of retarding recrystallization during hot rolling as a result of reprecipitation of manganese sulfide particles previously dissolved on heating for rolling. Laboratory tests are performed with the aim of determining the optimum heating temperature for rolling in order to implement the mechanism described.



Development of Steel Chemical Composition and Heat Treatment for Electrowelded Casings with Increased Strength and Cold Resistance
Abstract
Steel microalloying combinations are studied, and heat treatment regimes are determined for preparing the required level of mechanical properties providing high quality characteristics for steels used in the manufacture of casings of strength group K55 according to the API standard Spec 5CT, including cold resistance to −60°C.



Assimilation of New Steel Alloying Composition for Manufacturing Line Pipes of Strength Classes K52–K55
Abstract
The contemporary level of pipe rolling technology makes it possible to manufacture line pipes of strength class K42–K65 in corrosion- and cold-resistant versions. Pipes of this type are intended for building oil and gas pipelines that are used for developing fields, including those in the Far North. Avoidance of the main defects of both steel smelting and pipe rolling origin, revealed during pipe piercing and rolling, is an important problem for metallurgists in both domestic and overseas pipe plants. A reduction in scrap of metallurgical origin is facilitated by the use of advanced steel smelting technology in electric-arc furnaces followed by extra-furnace treatment and continuous billet casting. Steel 06GBA has been developed with the aim of improving pipe outer surface quality as a result of reducing carbon content and adding niobium. Replacement of steel grade 10GFBYu by steel 06GBA makes it possible to improve the output of finished pipes considerably.



Study of the Resistance of Steels 18KhMFB And 18Kh3MFB to Hot Deformation
Abstract
Experimental data are presented on the resistance of new steels 18KhMFB and 18Kh3MFB to deformation at temperatures of 1000 and 1150°C and strain rates of 0.05, 0.5, and 5 sec−1. A method of conducting experiments and analyzing the resulting data is described. The curves of deformation resistance that are obtained can be used for theoretical studies and modeling of hot-working processes in order to design technologies and equipment for the production of pump-compressor tubing.



Determination of Residual Ductility in the Forging of Bars on a Lever-Type Radial Forging Machine
Abstract
A method is proposed for determining the residual ductility of the material of a semifinished product. The method makes it possible to forge bars on a radial forging machine with the use of technically sound regimes for the reduction of semifinished products. The investigation that was performed involved both theoretical and experimental research. The theoretical part included determination of the stress state in the deformation zone in accordance with a new mathematical model, determination of the shear strain and ductility of the metal, and evaluation of its residual ductility in the forging of bars on a radial forging machine. In addition, an experiment was performed which involved the multi-pass forging of bars of different alloys with different reductions in each pass. The adequacy of the model was checked by comparing the calculated data with the experimental results obtained by forging bars made of different alloys.



Development of High-Temperature Nanostructured Silicate-Enamel Coatings for Enamelling Engineering Metalware
Abstract
The article considers high-temperature enamel coatings prepared from charges synthesizing enamel with a sufficiently high fi ring temperature and providing the required protective properties and heat resistance. Brief scientific and experimental research is given for the coatings obtained based on compositions modified with additions of refractory fillers added in the form of nanosize oxide powders.



Air-Tightness and Stability of Uglekon Type Carbon-Carbon Composite Materials in Corrosive Media
Abstract
Work is devoted to studying important efficiency indices of carbon-carbon composite materials of the Uglekon type, i.e., air-tightness and corrosion resistance in different corrosive media. Range characteristics are established for one of the main structural parameters, i.e., pyrocarbon coating thickness based on a slip underlayer of a supporting base of Uglekon material providing air-tightness, and consequently the efficiency of all composites under extreme high temperature and chemical activity conditions of corrosive media. The effect of thermal loads on air-tightness is also studied. Research results are entirely confirmed during approval of the composites developed on full-scale structures under severe conditions of high pressure, high temperature, and corrosive media, and long-term operating capacity is provided for the properties tested.



Feasibility Study of the Use of Nepheline-Limestone Charges Instead of Bauxite
Abstract
Nepheline is one of the raw materials used to produce alumina, which is the main component in the charge for the production of primary aluminum. Certain complications arise during the production process in the course of the charge’s heat treatment. This article discusses results of studies made of the formation of sublimates of alkali compounds during the dry sintering of a nepheline-limestone charge. It also addresses the matter of replacing imported “bauxite” alumina by Russian-made “nepheline” alumina. It is shown that a substantial portion of the sublimates is absorbed by the charge at different stages of its heat treatment. It is recommended that the remaining alkalis be taken out of the sintering operation by using a special bypass, which is similar to a practice employed in the production of Portland cement. The main theoretical results of the studies were corroborated in commercial trials performed together with the Danish company FLSmidth at its facilities in the U.S.



Example of an Expert Analysis of the Industrial Safety of Equipment
Abstract
An expert analysis of industrial safety is presented in the form of a case study. The analysis entailed determination of the following: the degree of agreement between the actual operating parameters of a BN2.8-16 drying drum and its design parameters; the technical condition of the dryer, with corroborating calculations. Recommendations were developed for continued use of the unit (drum).



Identification and Risk Assessment of Hazard Occurrence at the Aksu Ferroalloys Plant During 2007–2012
Abstract
This article is devoted to important aspects of preventing workplace trauma in the ferrous metallurgy industry of the Republic of Kazakhstan. The article focuses in particular on the Aksu Ferroalloys Plant, which is one of the largest factories in that industry. The use of Kinney’s method to evaluate workplace safety makes it possible to assess risks and implement the organizational, technical, and technological measures necessary to avoid hazardous situations that can lead to emergencies or accidents. Such measures reduce the number of injuries at factories.



Analysis of the Thermal State of a Semifinished Product During Hot Die Forging
Abstract
Results are presented from the use of numerical modeling to perform an empirical assessment of the effect of the initial process parameters in hot die forging (the temperatures to which the deforming tools and semifinished product are heated) on the temperature field in the semifinished product during deformation. A series of numerical experiments is performed on the basis of the finite-elements method, the resulting data are analyzed, and relationships between the parameters are established and explained.



Analysis of the Kinetics of the Solidification of Steel Forging Ingots of Different Configurations. Part II. Results from Computer Modeling*
Abstract
Results are presented from the use of computer modeling to study the effect of the configuration of forging ingots on the kinetics of their solidification. Aspects of the change in solidification rate in the vertical and horizontal directions over the ingot cross section are discussed, and calculations are performed to determine the solidification coefficients of steels as they harden in steel ingot molds. The results obtained by computer modeling are compared with results obtained by cold modeling.



Effect of the Parameters of the Technology Used to Make Multiphase Automotive Sheet Steels on the Degree of Assimilation of the Alloying Components
Abstract
The effect of process parameters in the production of progressive multiphase automobile steels on the assimilation of the elements used for alloying and microalloying is examined in order to develop an efficient steelmaking technology for this purpose, Data from the production and ladle treatment of 96 experimental heats of steels that are similar to these steels in chemical composition is statistically analyzed to improve these elements' assimilation by optimizing the regimes used for the addition of ferroalloys and other materials at different stages of the steels' treatment. It is established that the assimilation coefficients for Mn, Cr, Nb, V, and Si (to a lesser extent) are nearly independent of the timing and volume of the in-treatment additions of materials that contain these elements. On the other hand, the efficiency of the assimilation of Al and Ti depend to an appreciable extent on the type of material used and the treatment stage in which it is added. The results that are obtained are used to formulate a new approach to optimizing the addition of materials during the production of two-phase ferritic/martensitic steels of the HCT980X type. The adequacy of this approach was demonstrated by a trial heat that was made of this type of steel.



Kinetics of the Static Recrystallization of Austenite in Niobium-Microalloyed Pipe Steels
Abstract
A method is described for experimentally determining the parameters of a model of the kinetics of static recrystallization. Use of the method ensures a close correlation between calculated and experimental values of the percentage of recrystallized metal (R = 0.97). It is shown that the probability of the occurrence of partial recrystallization between roughing passes must be accounted for in order to evaluate the completeness with which static recrystallization takes place during multipass rolling. It was found that the kinetics of static recrystallization of niobium-microalloyed pipe steels depends on their chemical composition. A convenient software tool, HRRM (Hot Rolling Recrystallization Model), has been created to develop new rough-rolling regimes and correct existing such regimes for the controlled rolling of high-strength microalloyed steels.



Effect of Low-Carbon Steel 20GFL Heat Treatment Regime on Structure and Mechanical Properties
Abstract
Results are given for a study of the effect of heat treatment parameters on supercooled austenite transformation kinetics in steel 20GFL. Specimen microstructure is studied in specimens 10 × 10 mm in cross section with the following regimes: soaking at 860 and 940°C, cooling in an air stream 3–8 m/sec through a channel 100 mm in diameter. The change in microstructure features in the course of high-temperature soaking at 940°C for 30 and 60 min after specimen cooling in salt water is determined. It is established that in cast steel there is chemical composition microliquation inhomogeneity with respect to carbon and manganese, which decreases during soaking (60 min) and is accompanied by austenite grain growth. Critical cooling rates are determined with which a structure forms containing upper and lower bainite. A dependence is obtained for impact strength KCV−60 on soaking temperature and time in the γ-region. The effect is demonstrated of alloying with vanadium on the possibility of stimulating the formation of globular lower bainite components.



Thermodynamic Development of Austenite-Martensite Class Corrosion-Resistant Steels Intended for a Bimetal Cladding Layer
Abstract
Thermodynamic modeling is performed for regions of phase existence in economically alloyed corrosionresistant steels with the aim of determining the possibility of their use as a bimetal wear-resistant cladding layer. Quantitative evaluation is obtained for the form of nitrogen and oxygen present. It is demonstrated that for steels of the type in question introduction of niobium is only effective at the microalloying level.



Technology for Preparing Increased Strength Bimetal with a Nitrogen Two-Phase Steel Cladding Layer
Abstract
The possibility is considered for preparing bimetallic composite material (BCM) based on low-carbon microalloyed steel clad with corrosion-resistant steel alloyed with nitrogen. BCM mechanical and corrosion roperties are studied. It is shown that the material proposed is no worse than existing bimetals with respect to corrosion resistance, and concerning composite strength properties it surpasses traditional materials by 40–45%.



Study of Multiphase Automotive Sheet Steel Local Corrosion Resistance by Electrochemical Methods
Abstract
The nature of corrosion process development is studied by observing surface condition with potentiometric polarization. It is established that an increase in martensite content within steel structure increases the intensity of corrosion process development considerably. The high sensitivity of the corrosion test method developed to steel structural state (structural component content), and also prospects for using it instead of tests in accordance with GOST 9.911−89 are demonstrated.



High-Temperature Gas Extrusion as a Promising Method of Producing Preforms for Tool Steels
Abstract
Results are presented from an investigation of the structure and mechanical properties of tool steels R6M5 and EK-80 after their high-temperature gas extrusion (HTGE). It is shown that this treatment has a significant effect on steels’ phase composition, the structure of the phases that are formed, and, thus, the steels’ mechanical properties (hardness, ultimate strength, and ductility). It was determined that after undergoing HTGE at 1000–1150°C the steels have a hardness of 60–64 HRC and the same ductility as before the treatment. This makes it possible to use them to fabricate small tools by a simplified technology – single or double annealing of extruded semifinished products in the range 500–600°C without additional heating before quenching. Small tools made from such semifinished products last 2–3 times longer than tools made from cold-drawn rolled products.



Carbonitriding as a Means of Alleviating the Wear of Metallurgical Equipment Parts
Abstract
This article examines a technology used for surface-hardening – carbonitriding. Carbonitriding reduces the amount of labor involved in making equipment parts while also making them resistant to corrosion. This technology alleviates the wear of carbon-steel disks on a friction machine by a factor of 20–40 and results in a proportionate decrease in the wear of non-hardened shoes mated with the disks. The use of carbonitriding results in a manyfold reduction in the consumption of spare parts for metallurgical equipment. Among the important consequences of the decrease in the wear of parts are a reduction in repair costs, a decrease in the frequency of equipment repairs, and the generation of additional profit due to the accompanying increase in the equipment’s accrued operating time.



Intermetallic Compound Formation During Reaction of Molten Aluminum with Titanium
Abstract
A multistage process is described as the basis for metallographic studies of intermetallic formation during reaction of molten aluminum with titanium. A mechanism is proposed explaining the complex nature of the change in aluminide formation rate, including aluminide inclusion formation by breakdown. Stages are separated for reaction of titanium with molten aluminum: latent period; continuous intermetallic layer formation at a titanium-aluminum boundary; titanium dissolution in aluminum; band formation and growth within a melt with intermetallic fragments; increase in aluminide content in crystallizing melt. x-Ray structural and energy-dispersion analysis methods are used to demonstrate formation of just a single intermetallic TiAl3, which confirms thermodynamic calculations performed by Kattner.



Hot-Deformed Al–Ni Powder Materials Based on Alloy D-16 Mechanically-Activated Turnings
Abstract
Features are established for the effect of grinding parameters and saturated aqueous boric acid solution on charge grain size composition and physicomechanical properties of hot-deformed powder materials (HDPM) based on a mixture of aluminum powder and mechanochemically activated turning powder. Microanalysis and element mapping of areas are performed for HDPM with the optimum set of mechanical properties, and HDPM structure with improved mechanical properties is also demonstrated.



Plasma Welding of Aluminum Alloys with the Use of Two Direct ARCS on Reverse-Polarity Current
Abstract
The use of plasma-based technologies elevates productivity and product quality in the fabrication of welded structures made of aluminum and its alloys. High-power heat sources must be used to achieve high levels of productivity in the welding of aluminum structures. Also, the presence of an oxide fi lm that impedes the formation of the weld dictates the use of reverse-polarity current in the arc welding of such structures. The use of combination heat sources can resolve the problem of improving quality and productivity in the welding of aluminum alloys. This article presents results from a study of the plasma welding of aluminum alloys with the use of a dual-arc plasmotron that provides for the combustion of two direct arcs on reversepolarity current. It is shown that the plasmotron can operate stably under these conditions. Use of the given technology reduces the thermal load on the plasmotron, enhances its ability to melt through the alloys, improves cathodic cleaning of the metal’s surface in the region of the weld, and ensures the formation of welds that are free of defects.



The Development of Steel Band Feeding for HSLA Heavy Plates
Abstract
Advanced technology has been developed for the production of HSLA steel heavy plates over 60 mm thick made from concast slabs. This technology provides steel band feeding to the concaster mould liquid pool by a specially designed device. The developed technology is a convenient tool for optimization of the casting macrostructure. Minimization of the axial segregation and heavy plate Z-direction mechanical property improvement were realized even if the reduction ratio was less than 2–3. The ductility in the Z-direction of heavy plates was increased by 15–20%, and the toughness of heavy plates was increased by 1.5–2.0 times. High level yield (97.5–99.5%) was reached for heavy plates by the implementation of steel band feeding on the basis of ultrasonic tests using European standard SEL 072 class 1–2. Therefore, steel band feeding is an appropriate alternative to soft reduction and electromagnetic stirring technologies for heavy HSLA steel plates.


