The Local Structure and Hydration Processes of Halogen-Substituted Perovskites Based on Ba4In2Zr2O11


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Halogen-substituted perovskites Ba4In2Zr2O10.95F0.1 and Ba4In2Zr2O10.95Cl0.1 are synthesized, and their single-phase composition is verified by X-ray diffraction analysis. Their ability of the studied phases to hydrate and form energetically unequal OH groups is proved. It is found that introduction of halide ions leads to a decrease in the hydration degree with respect to the matrix composition, which is explained by a decrease in the crystal unit cell free volume Processes.

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N. Tarasova

Institute of Natural Sciences and Mathematics,
Ural Federal University Named after the First President of Russia B.N. Yeltsin

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Email: Natalia.Tarasova@urfu.ru
俄罗斯联邦, Yekaterinburg, 620026

A. Galisheva

Institute of Natural Sciences and Mathematics,
Ural Federal University Named after the First President of Russia B.N. Yeltsin

Email: Natalia.Tarasova@urfu.ru
俄罗斯联邦, Yekaterinburg, 620026

I. Animitsa

Institute of Natural Sciences and Mathematics,
Ural Federal University Named after the First President of Russia B.N. Yeltsin

Email: Natalia.Tarasova@urfu.ru
俄罗斯联邦, Yekaterinburg, 620026

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