Email this article Synthesis and study of ternary molybdates RbCaR(MoO4)3 with a scheelite-like structure in Rb2MoO4–CaMoO4–R2(MoO4)3 systems (R = Nd, Sm, Eu, Gd)
- Authors: Kozhevnikova N.M.1
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Affiliations:
- Baikal Institute of Nature Management, Siberian Branch
- Issue: Vol 61, No 12 (2016)
- Pages: 1518-1521
- Section: Synthesis and Properties of Inorganic Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/166946
- DOI: https://doi.org/10.1134/S0036023616120081
- ID: 166946
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Abstract
Phase ratios in the subsolidus regions of Rb2MoO4–CaMoO4–R2(MoO4)3 systems (R = Nd, Sm, Eu, or Gd) were studied by vibrational spectroscopy, X-ray diffraction, and differential thermal analysis. Ternary molybdates RbCaR(MoO4)3 (R = Nd, Sm, Eu, Gd) with scheelite derivative structures (monoclinic symmetry system, space group P21/n) were synthesized. Unit cell parameters were determined, and IR and Raman spectra were characterized.
About the authors
N. M. Kozhevnikova
Baikal Institute of Nature Management, Siberian Branch
Author for correspondence.
Email: nicas@binm.bscnet.ru
Russian Federation, ul. Sakh’yanovoi 8, Ulan-Ude, Republic of Buryatia, 670047
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