Email this article Methane Adsorption on Cu-BTC110 Metal-Organic Framework
- Authors: Knyazeva M.K.1, Vysotskii V.V.1, Shiryaev A.A.1, Pulin A.L.1, Men’shchikov I.E.1, Shkolin A.V.1, Fomkin A.A.1, Tsivadze A.Y.1, Solovtsova O.V.1, Kiselev M.R.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Issue: Vol 64, No 12 (2019)
- Pages: 1507-1512
- Section: Synthesis and Properties of Inorganic Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/169586
- DOI: https://doi.org/10.1134/S0036023619120064
- ID: 169586
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Abstract
Cu-BTC110 metal-organic framework has been synthesized by solvothermal method using N,N '‑dimethylformamide organic solvent at 110°C. Cu-BTC110 sample has the following adsorption characteristics: micropore volume W0 = 0.38 cm3/g, specific surface area SBET = 850 m2/g, micropore radius х0 = 0.36 nm, standard characteristic energy of benzene adsorption Е0 = 33.6 kJ/mol. Methane adsorption on a Cu-BTC110 sample at temperature from 210 to 293 K and pressure up to 140 kPa has been studied. Differential molar heat of methane adsorption has been calculated from adsorption isosteres.
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About the authors
M. K. Knyazeva
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Author for correspondence.
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
V. V. Vysotskii
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
A. A. Shiryaev
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
A. L. Pulin
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
I. E. Men’shchikov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
A. V. Shkolin
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
A. A. Fomkin
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
O. V. Solovtsova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
M. R. Kiselev
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: batrakovamk@mail.ru
Russian Federation, Moscow, 119991
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