Magnesium(II) and cadmium(II) octaphenyltetraazaporphyrinates in metal exchange reaction with MnCl2 in DMSO


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Resumo

Reaction kinetics of metal exchange of Mg(II) and Cd(II) octaphenyltetraazaporphynates with MnCl2 in DMSO has been studied by spectrophotometry. Kinetic parameters of the metal exchange reaction have been determined. Possible stoichiometric reaction mechanism has been suggested. Effect of solvent and salt solvate nature on the rate of metal exchange reaction has been revealed.

Sobre autores

S. Zvezdina

Krestov Institute of Solution Chemistry

Autor responsável pela correspondência
Email: svvr@isc-ras.ru
Rússia, Ivanovo, 153045

N. Chizhova

Krestov Institute of Solution Chemistry

Email: svvr@isc-ras.ru
Rússia, Ivanovo, 153045

N. Mamardashvili

Krestov Institute of Solution Chemistry

Email: svvr@isc-ras.ru
Rússia, Ivanovo, 153045

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