Мақаланы E-mail арқылы жіберу Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy
- Авторлар: Demina L.I.1,2, Kuz’mina L.G.2, Demin S.V.1,2, Shokurova N.A.1, Zhilov V.I.1,2, Tsivadze A.Y.1,2
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Мекемелер:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Шығарылым: Том 62, № 11 (2017)
- Беттер: 1536-1543
- Бөлім: Physical Chemistry of Solutions
- URL: https://journal-vniispk.ru/0036-0236/article/view/168193
- DOI: https://doi.org/10.1134/S0036023617110031
- ID: 168193
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Аннотация
The complex formation of lithium with benzo-15-crown-5 (B15C5) was investigated. The complexes LiB15C5H2OX, where X = Cl− (1), I− (2), (3), (5), and LiBF4B15C5 (4) were synthesized and studied by IR spectroscopy. Complexes 1–4 were examined by X-ray diffraction. According to IR spectroscopy data, the crown ether conformation changes upon dissolution. The interaction of the extracted complex with the solvent was identified.
Авторлар туралы
L. Demina
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Ресей, Moscow, 119071; Moscow, 119991
L. Kuz’mina
Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Ресей, Moscow, 119991
S. Demin
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Ресей, Moscow, 119071; Moscow, 119991
N. Shokurova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Ресей, Moscow, 119071
V. Zhilov
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Хат алмасуға жауапты Автор.
Email: zhilov@igic.ras.ru
Ресей, Moscow, 119071; Moscow, 119991
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Ресей, Moscow, 119071; Moscow, 119991
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