Отправить статью по E-mail Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy
- Авторы: Demina L.I.1,2, Kuz’mina L.G.2, Demin S.V.1,2, Shokurova N.A.1, Zhilov V.I.1,2, Tsivadze A.Y.1,2
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Учреждения:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Выпуск: Том 62, № 11 (2017)
- Страницы: 1536-1543
- Раздел: Physical Chemistry of Solutions
- URL: https://journal-vniispk.ru/0036-0236/article/view/168193
- DOI: https://doi.org/10.1134/S0036023617110031
- ID: 168193
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Аннотация
The complex formation of lithium with benzo-15-crown-5 (B15C5) was investigated. The complexes LiB15C5H2OX, where X = Cl− (1), I− (2), (3), (5), and LiBF4B15C5 (4) were synthesized and studied by IR spectroscopy. Complexes 1–4 were examined by X-ray diffraction. According to IR spectroscopy data, the crown ether conformation changes upon dissolution. The interaction of the extracted complex with the solvent was identified.
Об авторах
L. Demina
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Россия, Moscow, 119071; Moscow, 119991
L. Kuz’mina
Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Россия, Moscow, 119991
S. Demin
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Россия, Moscow, 119071; Moscow, 119991
N. Shokurova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Россия, Moscow, 119071
V. Zhilov
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: zhilov@igic.ras.ru
Россия, Moscow, 119071; Moscow, 119991
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Россия, Moscow, 119071; Moscow, 119991
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