Structural Features of Monomeric Octahedral Monooxo d2-Rhenium(V) Complexes [ReO(Ln)2(Lmono)] with Oxygen Atoms of Bidentate Chelate O,N Ligands (Ln): 1. Complexes with Five-Membered Chelate Rings ReNC2O

Аннотация

The structural features of 14 mononuclear d²-Re(V) octahedral monooxo complexes with mono-charged oxygen atoms of bidentate chelate (O, N) ligands (Lⁿ) of the general formula [ReO(Lⁿ)₂(L_mono)] (L_mono is a monodentate ligand) containing five-membered chelate rings ReNC₂O are discussed. The O(Lⁿ) atoms are in the trans positions to the O(oxo) ligands.