Отправить статью по E-mail Synthesis and Investigation of Thermodynamic Properties of Cu5V2O10
- Авторы: Galiakhmetova N.A.1, Denisov V.M.1, Denisova L.T.1, Kargin Y.F.2, Belousova N.V.1
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Учреждения:
- Institute of Non-ferrous Metals and Materials Science
- Baikov Institute of Metallurgy and Materials Science
- Выпуск: Том 64, № 6 (2019)
- Страницы: 725-728
- Раздел: Synthesis and Properties of Inorganic Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/169378
- DOI: https://doi.org/10.1134/S0036023619060056
- ID: 169378
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Аннотация
Cu5V2O10 is prepared by solid-phase synthesis via sequential air calcination of a stoichiometric CuO-V2O5 mixture. Its high-temperature heat capacity is measured by differential scanning calorimetry. The thermodynamic properties (enthalpy and entropy changes and scaled Gibbs free energy) are calculated using the experimental dependence Cp =f(T). It is shown that specific heat capacity correlates with the composition of oxides in the CuO−V2O5 system.
Об авторах
N. Galiakhmetova
Institute of Non-ferrous Metals and Materials Science
Email: antluba@mail.ru
Россия, Krasnoyarsk, 660041
V. Denisov
Institute of Non-ferrous Metals and Materials Science
Email: antluba@mail.ru
Россия, Krasnoyarsk, 660041
L. Denisova
Institute of Non-ferrous Metals and Materials Science
Автор, ответственный за переписку.
Email: antluba@mail.ru
Россия, Krasnoyarsk, 660041
Yu. Kargin
Baikov Institute of Metallurgy and Materials Science
Email: antluba@mail.ru
Россия, Moscow, 119991
N. Belousova
Institute of Non-ferrous Metals and Materials Science
Email: antluba@mail.ru
Россия, Krasnoyarsk, 660041
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