Effect of the cooling rate on the phase composition of crystallized CdGeAs2 melts


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The formation of metastable Cd3Ge2As4 was established using a set of physicochemical analysis methods. The annealing of this compound at temperatures ≥450°C was shown to lead to the formation of the stable binary eutectic Cd3As2–СdGeAs2 and ternary eutectic Cd3As2–СdGeAs2–CdAs2 with the following composition (at %): Cd, 42.20; Ge, 15.69; As, 42.11; and Cd, 42.70; Ge, 15.06; As, 42.24, respectively.

作者简介

A. Aronov

Kurnakov Institute of General and Inorganic Chemistry

Email: marenkin@rambler.ru
俄罗斯联邦, Moscow, 119991

S. Marenkin

Kurnakov Institute of General and Inorganic Chemistry; National University of Science and Technology “Moscow Institute of Steel and Alloys”

编辑信件的主要联系方式.
Email: marenkin@rambler.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

I. Fedorchenko

Kurnakov Institute of General and Inorganic Chemistry

Email: marenkin@rambler.ru
俄罗斯联邦, Moscow, 119991

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