Conductivity and electrochemical stability of concentrated aqueous choline chloride solutions
- Авторы: Grishina E.P.1,2, Kudryakova N.O.1
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Учреждения:
- Krestov Institute of Solution Chemistry
- Ivanovo State University of Chemistry and Technology
- Выпуск: Том 91, № 10 (2017)
- Страницы: 2024-2028
- Раздел: Colloid Chemistry and Electrochemistry
- URL: https://journal-vniispk.ru/0036-0244/article/view/169742
- DOI: https://doi.org/10.1134/S0036024417100144
- ID: 169742
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Аннотация
The conductivity and electrochemical stability of choline chloride (ChCl) solutions with water contents ranging from 20 to 39 wt % are studied. Exposing ChCl to moist ambient air yields a highly concentrated aqueous solution that, as an electrolyte, exhibits the properties and variations in conductivity with temperature and concentration characteristic of other similar systems. Its electrochemical stability window, determined by cyclic voltammetry, is comparable to that of ChCl-based deep eutectic solvents (DESs). Products of the electrolysis of ChCl‒H2O mixtures seem to be less toxic than those of Reline, Ethaline, and Maline.
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Об авторах
E. Grishina
Krestov Institute of Solution Chemistry; Ivanovo State University of Chemistry and Technology
Автор, ответственный за переписку.
Email: epg@isc-ras.ru
Россия, Ivanovo, 153045; Ivanovo, 153000
N. Kudryakova
Krestov Institute of Solution Chemistry
Email: epg@isc-ras.ru
Россия, Ivanovo, 153045
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