Kinetics and mechanism of olefin catalytic hydroalumination by organoaluminum compounds
- Авторлар: Koledina K.F.1, Gubaidullin I.M.1
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Мекемелер:
- Institute of Petrochemistry and Catalysis
- Шығарылым: Том 90, № 5 (2016)
- Беттер: 914-921
- Бөлім: Chemical Kinetics and Catalysis
- URL: https://journal-vniispk.ru/0036-0244/article/view/168124
- DOI: https://doi.org/10.1134/S0036024416050186
- ID: 168124
Дәйексөз келтіру
Аннотация
The complex reaction mechanism of α-olefin catalytic hydroalumination by alkylalanes is investigated via mathematical modeling that involves plotting the kinetic models for the individual reactions that make up a complex system and a separate study of their principles. Kinetic parameters of olefin catalytic hydroalumination are estimated. Activation energies of the possible steps of the schemes of complex reaction mechanisms are compared and possible reaction pathways are determined.
Негізгі сөздер
Авторлар туралы
K. Koledina
Institute of Petrochemistry and Catalysis
Хат алмасуға жауапты Автор.
Email: koledinakamila@mail.ru
Ресей, Ufa, 450075
I. Gubaidullin
Institute of Petrochemistry and Catalysis
Email: koledinakamila@mail.ru
Ресей, Ufa, 450075
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