Physicochemical properties of the surfaces of silica species


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The results from studying the physicochemical characteristics of the adsorption of n-alkanes, arenes, and acetonitrile on silicas of different origins, silica gels, and silochromes are presented. It is shown that increasing the concentration of silanol groups reduces the role of dispersion interactions accompanied by the intensification of specific interactions on silica gels, compared to silochromes. According to diffuse reflectance FTIR spectroscopy data, the acidity of silanol groups on silica gel is in this case less pronounced.

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T. Roshchina

Department of Chemistry

编辑信件的主要联系方式.
Email: 2474747@mail.ru
俄罗斯联邦, Moscow, 119992

N. Shoniya

Department of Chemistry

Email: 2474747@mail.ru
俄罗斯联邦, Moscow, 119992

O. Tegina

Department of Chemistry

Email: 2474747@mail.ru
俄罗斯联邦, Moscow, 119992

O. Tkachenko

Zelinsky Institute of Organic Chemistry

Email: 2474747@mail.ru
俄罗斯联邦, Moscow, 119991

L. Kustov

Department of Chemistry; Zelinsky Institute of Organic Chemistry

Email: 2474747@mail.ru
俄罗斯联邦, Moscow, 119992; Moscow, 119991

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