Simulation of the potentiodynamic and galvanostatic phase formation in melts


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Resumo

A general scheme is used to consider the initial stages of electrocrystallization under potentiodynamic and galvanostatic conditions. Proposed theoretical models are shown to agree well with the experimental results obtained during the electrodeposition of silver crystals on an iridium microelectrode from nitrate melt containing an excess background electrolyte.

Sobre autores

V. Isaev

Institute of High-Temperature Electrochemistry, Ural Branch

Autor responsável pela correspondência
Email: v.isaev@ihte.uran.ru
Rússia, ul. S. Kovalevskaya 22/ul. Akademicheskaya 20, Yekaterinburg, 620137

O. Grishenkova

Institute of High-Temperature Electrochemistry, Ural Branch

Email: v.isaev@ihte.uran.ru
Rússia, ul. S. Kovalevskaya 22/ul. Akademicheskaya 20, Yekaterinburg, 620137

A. Kosov

Institute of High-Temperature Electrochemistry, Ural Branch

Email: v.isaev@ihte.uran.ru
Rússia, ul. S. Kovalevskaya 22/ul. Akademicheskaya 20, Yekaterinburg, 620137

O. Semerikova

Institute of High-Temperature Electrochemistry, Ural Branch

Email: v.isaev@ihte.uran.ru
Rússia, ul. S. Kovalevskaya 22/ul. Akademicheskaya 20, Yekaterinburg, 620137

Yu. Zaykov

Institute of High-Temperature Electrochemistry, Ural Branch

Email: v.isaev@ihte.uran.ru
Rússia, ul. S. Kovalevskaya 22/ul. Akademicheskaya 20, Yekaterinburg, 620137

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