The crystallization temperature of vein quartz estimated from the concentration of the titanium paramagnetic center in quartz: A case study of the Peschanka porphyry copper–molybdenum–gold deposit, Western Chukchi Peninsula, Russia

Abstract

The concentration of the Al and Ti paramagnetic impurity centers in pre-ore and ore-stage quartz at the Peschanka porphyry copper–molybdenum–gold deposit in the Western Chukchi Peninsula, Russia were determined using electron paramagnetic resonance spectroscopy (EPR). The [AlO₄^-/h⁺]⁰ concentration in pre-ore and ore-stage quartz varies from 29 to 124 and from 13 to 101 at. ppm, respectively. The contents of the [TiO₄^-/Li⁺]⁰ and [TiO₄^-/H⁺]⁰ centers reach 20 and 6.3 at. ppm, respectively. Pre-ore quartz associated with the formation of biotite–potassium feldspar–quartz alteration and ore-stage quartz associated with the formation of quartz–sericite rocks followed by the ore deposition differ considerably in the Ti center content, especially the [TiO₄^-/H⁺]⁰ center. The [TiO₄^-/H⁺]⁰ concentration is much higher in the pre-ore quartz (>2 at. ppm) than that in the ore-stage quartz related to copper mineralization (<2 at. ppm). The [TiO₄^-/Li⁺]⁰ concentration also decreases from pre-ore to ore-stage quartz. Taking the data we obtained into account, the formation temperature of pre-ore and ore-stage quartz estimated from a titaniumin-quartz geothermometer is 590–470°C (weighted average 520°C) and 510–310°C (weighted average 430°C), respectively. The obtained temperature range of 590 to 310°C is similar to that determined from homogenization of fluid inclusions in quartz.