Enviar artigo por via de e-mail ELECTROCHEMICAL LITHIATION OF NICKEL PHYLLOSILICATE NANOSCROLLS IN THE 0.01–4.5 V VOLTAGE RANGE
- Autores: Кrasilina D.A1, Larosh P.V1, Khrapova E.K1, Rumyantsev A.M1, Krasilin A.A1
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Afiliações:
- Ioffe Institute, Politekhnicheskaya st. 26
- Edição: Volume 61, Nº 9 (2025)
- Páginas: 500–513
- Seção: Специальный выпуск “Электрохимия на ХХII Менделеевском съезде общей и прикладной химии”, октябрь 2024 г., Сириус, РФ
- URL: https://journal-vniispk.ru/0424-8570/article/view/376648
- DOI: https://doi.org/10.7868/S3034618525090064
- ID: 376648
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Resumo
Here, we study processes of Li insertion into Ni3Si2O5(OH)4 phyllosilicate nanoscrolls in the 0.01–4.5 V voltage range aiming to establish electrochemical reactions and reveal the reasons of electrode degradation. The first cathodic polarization initiates the phyllosilicate crystal structure destruction with formation of NiO, and probably SiO2 and Si, capable of reversible interaction with lithium. As cycling proceeds, the electrode capacity decreases, and the cathodic/anodic processes voltages change. The main cause of the degradation of nickel phyllosilicate-based electrodes is a decrease in the electrochemical activity of nickel oxide and its gradual transition first to cubic LixNi2–xO2 and then to hexagonal LiNiO2.
Sobre autores
D. Кrasilina
Ioffe Institute, Politekhnicheskaya st. 26
Email: d.a.krasilina@mail.ioffe.ru
Saint Petersburg, Russia
P. Larosh
Ioffe Institute, Politekhnicheskaya st. 26
Email: d.a.krasilina@mail.ioffe.ru
Saint Petersburg, Russia
E. Khrapova
Ioffe Institute, Politekhnicheskaya st. 26
Email: d.a.krasilina@mail.ioffe.ru
Saint Petersburg, Russia
A. Rumyantsev
Ioffe Institute, Politekhnicheskaya st. 26
Autor responsável pela correspondência
Email: d.a.krasilina@mail.ioffe.ru
Saint Petersburg, Russia
A. Krasilin
Ioffe Institute, Politekhnicheskaya st. 26
Email: ikrasilin@mail.ioffe.ru
Saint Petersburg, Russia
Bibliografia
- Храпова, Е.К., Ежов, И.С., Румянцев, А.М., Жданов, В.В., Красилин, А.А. Нанотубулярный гидросиликат никеля и продукты его термического отжига в качестве анодных материалов литий-ионных аккумуляторов. Неорганические материалы. 2020. Т. 56. С. 1317. @@Khrapova, E.K., Ezhov, I.S., Rumyantsev, A.M., Zhdanov, V.V., and Krasilin, A.A., Nanotubular nickel hydrosilicate and Its thermal annealing products as anode materials for lithium ion batteries, Inorg. Mater., 2020, vol. 56, p. 1248.
- Иванищев, А.В., Чуриков, А.В., Иванищева, И.А., Запсис, К.В., Гамаюнова, И.М. Импедансная спектроскопия литий-углеродных электродов. Электрохимия. 2008. Т. 44. С. 553. @@Ivanishchev, A.V., Churikov, A.V., Ivanishcheva, I.A., Zapsis, K.V., and Gamayunova, I.M., Impedance spectroscopy of lithium-carbon electrodes, Russ. J. Electrochem., 2008, vol. 44, p. 533.
- Кулова, Т.Л., Скундин, А.М., Плесков, Ю.В., Теруков, Е.И., Коньков, О.И. Исследование интеркаляции лития в тонкие пленки аморфного кремния. Электрохимия. 2006. Т. 42. С. 414. @@Kulova, T.L., Skundin, A.M., Pleskov, Yu.V., Terukov, E.I., and Kon’kov, O.I., Lithium intercalation in thin amorphous-silicon films, Russ. J. Electrochem., 2006, vol. 42, p. 363.
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