Мақаланы E-mail арқылы жіберу Multiplet-Matched Filtering of 103Rh Signal Using Information Contained in 31P Spectrum of AA′XX′ 31P–103Rh Spin System
- Авторлар: Podkorytov I.S.1, Cherkasova T.G.2, Kayfadzhyan E.A.3, Varshavsky Y.S.2
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Мекемелер:
- Laboratory of Biomolecular NMR, St. Petersburg State University
- Institute of Chemistry, St. Petersburg State University
- D. I. Mendeleyev Institute for Metrology
- Шығарылым: Том 50, № 4 (2019)
- Беттер: 563-568
- Бөлім: Original Paper
- URL: https://journal-vniispk.ru/0937-9347/article/view/248311
- DOI: https://doi.org/10.1007/s00723-018-1083-1
- ID: 248311
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Аннотация
Splitting parameters measured in the sensitive 31P part of an AA′XX′ 31P–103Rh spectrum make it possible to perform a multiplet-matched digital filtering of the weak 103Rh free induction decay signal. Compared to the conventional matched exponential weighting, this multiplet-matched filtering has provided a gain of 1.8 ± 0.4 in the signal-to-noise ratio of the experimental rhodium spectrum. The maximum gain predicted theoretically is equal to 2.
Авторлар туралы
I. Podkorytov
Laboratory of Biomolecular NMR, St. Petersburg State University
Хат алмасуға жауапты Автор.
Email: podkorytov@rambler.ru
Ресей, St. Petersburg, 199034
T. Cherkasova
Institute of Chemistry, St. Petersburg State University
Email: podkorytov@rambler.ru
Ресей, St. Petersburg, 199034
E. Kayfadzhyan
D. I. Mendeleyev Institute for Metrology
Email: podkorytov@rambler.ru
Ресей, St. Petersburg, 190005
Yu. Varshavsky
Institute of Chemistry, St. Petersburg State University
Email: podkorytov@rambler.ru
Ресей, St. Petersburg, 199034
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