Influence of alkylation parameters, feedstock composition, and catalyst type on the ortho/para ratio of resulting alkylphenols

S. V. Kotov; V. A. Tyshchenko; I. M. Zerzeva; A. V. Tarasov; G. V. Timofeeva; N. S. Kotova

doi:10.1134/S0965544117020165

Influence of alkylation parameters, feedstock composition, and catalyst type on the ortho/para ratio of resulting alkylphenols

作者: Kotov S.V.¹, Tyshchenko V.A.¹, Zerzeva I.M.², Tarasov A.V.², Timofeeva G.V.¹, Kotova N.S.¹
隶属关系:
1. Middle Volga Oil Refining Research Institute
2. Novokuibyshevsk Lubricants and Additives Plant
期: 卷 57, 编号 3 (2017)
页面: 257-261
栏目: Article
URL: https://journal-vniispk.ru/0965-5441/article/view/179144
DOI: https://doi.org/10.1134/S0965544117020165
ID: 179144

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It has been found that process time and temperature affect the isomer ratio of alkylphenols depending on the catalyst type. Phenol alkylation with linear α-olefins leads a prevalence of ortho-alkylphenols over the para-isomers, unlike the case of branched olefins.