Enviar artigo por via de e-mail Chemistry of Dimethyl Ether: Catalytic Synthesis of 1,3-Butadiene
- Autores: Khadzhiev S.N.1, Maksimov A.L.1, Tret’yakov V.F.1, Talyshinskii R.M.1, Ilolov A.M.1
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Afiliações:
- Topchiev Institute of Petrochemical Synthesis
- Edição: Volume 58, Nº 8 (2018)
- Páginas: 613-621
- Seção: Article
- URL: https://journal-vniispk.ru/0965-5441/article/view/180275
- DOI: https://doi.org/10.1134/S096554411808011X
- ID: 180275
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Resumo
Catalytic synthesis of 1,3-butadiene from dimethyl ether (DME) has been carried out for the first time. It has been established that 1,3-butadiene forms via three possible routes of reactions between DME conversion products: by reaction of propylene with formaldehyde according to the Prins condensation mechanism, by DME isomerization of to ethanol followed by its conversion to 1,3-butadiene through acetaldehyde, and by dehydrogenation of butylenes.
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Sobre autores
S. Khadzhiev
Topchiev Institute of Petrochemical Synthesis
Email: talyshinsky@list.ru
Rússia, Moscow, 119991
A. Maksimov
Topchiev Institute of Petrochemical Synthesis
Email: talyshinsky@list.ru
Rússia, Moscow, 119991
V. Tret’yakov
Topchiev Institute of Petrochemical Synthesis
Email: talyshinsky@list.ru
Rússia, Moscow, 119991
R. Talyshinskii
Topchiev Institute of Petrochemical Synthesis
Autor responsável pela correspondência
Email: talyshinsky@list.ru
Rússia, Moscow, 119991
A. Ilolov
Topchiev Institute of Petrochemical Synthesis
Email: talyshinsky@list.ru
Rússia, Moscow, 119991
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