Effect of Binder on the Properties of MWW Zeolite Catalysts in Benzene Alkylation with Propylene


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The effect of the nature of the binding component (Al2O3, SiO2, kaolin) on the physicochemical and catalytic properties of catalysts based on a hierarchical zeolite of the MWW framework type in benzene alkylation with propylene has been studied. The best results have been obtained using Al(OH)3 as an Al2O3 precursor. This precursor does not have an adverse effect on the acidic properties of the catalyst and thereby provides an increase in the yield of the desired product, i.e., cumene. The addition of kaolin to this catalyst does not affect the strength characteristics; however, the presence of this binder leads to a decrease in the number of acid sites in the sample.

作者简介

I. Gerzeliev

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: gerzeliev@ips.ac.ru
俄罗斯联邦, Moscow, 119991

V. Zhmylev

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: gerzeliev@ips.ac.ru
俄罗斯联邦, Moscow, 119991

D. Khusaimova

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: gerzeliev@ips.ac.ru
俄罗斯联邦, Moscow, 119991

A. Shkuropatov

Faculty of Chemistry, Moscow State University

Email: gerzeliev@ips.ac.ru
俄罗斯联邦, Moscow, 119991

E. Knyazeva

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University

Email: gerzeliev@ips.ac.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

O. Ponomareva

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University

Email: gerzeliev@ips.ac.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

I. Ivanova

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University

Email: gerzeliev@ips.ac.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

A. Maksimov

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: gerzeliev@ips.ac.ru
俄罗斯联邦, Moscow, 119991

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