The use of potassium iodide solution as photochemical actinometer for vacuum ultraviolet region


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The paper has investigated the process of measuring power illumination for vacuum ultraviolet radiation by means of the solution of potassium iodide as a photochemical actinometer. We have investigated the formation of triiodide–ion when radiated the solution of light with wavelength 185 nm. It has been shown that obtaining hydroxyl radicals OH at this wavelength is determined by the formation of I3. The quantum yield of the process constitutes 0.165. Measuring the concentration of the obtained I3 we determined power illumination of a quartz lamp DRB-20 (wavelength 185 nm), which constitutes 49.2 × 10–9 E/s.

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A. Mamaenko

Dumanskii Institute of Colloid Chemistry and the Chemistry of Water

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Email: mamaenko_1407@ukr.net
乌克兰, Kiev

A. Todorov

Dumanskii Institute of Colloid Chemistry and the Chemistry of Water

Email: mamaenko_1407@ukr.net
乌克兰, Kiev

O. Zui

Dumanskii Institute of Colloid Chemistry and the Chemistry of Water

Email: mamaenko_1407@ukr.net
乌克兰, Kiev

V. Yaremenko

Dumanskii Institute of Colloid Chemistry and the Chemistry of Water

Email: mamaenko_1407@ukr.net
乌克兰, Kiev

V. Goncharuk

Dumanskii Institute of Colloid Chemistry and the Chemistry of Water

Email: mamaenko_1407@ukr.net
乌克兰, Kiev

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