Effect of metal impurities on the oxidation of various carbon forms in products of detonation diamond synthesis


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The optimal catalyst for a selective oxidation of the nondiamond component of a diamond detonation synthesis product has been determined. The phase composition and oxidation resistance of diamond nanopowders recovered by different methods have been studied. It has been shown the existence of residual nondiamond carbon in diamond powders recovered by a gas-phase oxidation in the presence of copper (II) chloride (CuCl2) and their higher oxidation resistance than of recovered by a mixture of chromium anhydride with the sulphate acid.

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A. Panova

Bakul Institute for Superhard Materials

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Email: annpanova@ukr.net
乌克兰, vul. Avtozavods’ka 2, Kiev, 04074

G. Bogatyreva

Bakul Institute for Superhard Materials

Email: annpanova@ukr.net
乌克兰, vul. Avtozavods’ka 2, Kiev, 04074

V. Zabuga

Shevchenko Kiev National University

Email: annpanova@ukr.net
乌克兰, vul. Volodymyrs’ka 64, Kiev, 01601

G. Tsapyuk

Shevchenko Kiev National University

Email: annpanova@ukr.net
乌克兰, vul. Volodymyrs’ka 64, Kiev, 01601

M. Serga

Bakul Institute for Superhard Materials

Email: annpanova@ukr.net
乌克兰, vul. Avtozavods’ka 2, Kiev, 04074

O. Byeda

Shevchenko Kiev National University

Email: annpanova@ukr.net
乌克兰, vul. Volodymyrs’ka 64, Kiev, 01601

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