Email this article Synthesis, structure, and magnetic properties of a YbIII complex with the iminopyridine radical-anionic ligand
- Authors: Trifonov A.A.1,2, Shestakov B.G.2, Lyubov D.M.2, Lyssenko K.A.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
- Issue: Vol 67, No 1 (2018)
- Pages: 50-55
- Section: Article
- URL: https://journal-vniispk.ru/1066-5285/article/view/241904
- DOI: https://doi.org/10.1007/s11172-018-2036-4
- ID: 241904
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Abstract
The reaction of equimolar amounts of ytterbocene (C5Me4H)2Yb(THF)2 and iminopyridine 2,6-Pri2C6H3N=CH(C5H4N) accompanied by the one-electron oxidation of the ytterbium ion produced the unique lanthanide complex (C5Me4H)2YbIII[2,6-Pri2-C6H3NCH(C5H4N)]–• with the iminopyridine radical-anionic ligand. The structure of the complex in the crystalline state was established by X-ray diffraction and its magnetic properties were studied in the temperature range of 1.8—300 K.
About the authors
A. A. Trifonov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: trif@iomc.ras.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991; 49 ul. Tropinina, Nizhny Novgorod, 603137
B. G. Shestakov
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: trif@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603137
D. M. Lyubov
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: trif@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603137
K. A. Lyssenko
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: trif@iomc.ras.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
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