Email this article Chiral guest in a chiral framework: X-ray diffraction study
- Authors: Zavakhina M.S.1,2, Khan I.S.1, Barsukova M.O.1,2, Sapianik A.A.1,2, Samsonenko D.G.1,2, Dybtsev D.N.1,2, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 67, No 7 (2018)
- Pages: 1268-1272
- Section: Article
- URL: https://journal-vniispk.ru/1066-5285/article/view/242719
- DOI: https://doi.org/10.1007/s11172-018-2211-7
- ID: 242719
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Abstract
The inclusion compound of zinc lactate terephthalate with R-butan-2-ol, [Zn2(R-BusOH) (bdc)(S-lac)]•(R-BusOH) (BusOH is butan-2-ol, H2bdc is terephthalic acid, S-H2lac is lactic acid), was prepared by soaking crystals of [Zn2(dmf)(bdc)(S-lac)]•DMF in pure R-butan-2-ol. The positions of chiral alcohol molecules in voids of the chiral framework and the host–guest contacts were determined by X-ray diffraction. These data provide an explanation for the origin of chiral discrimination of zinc lactate terephthalate toward the R-isomer of butan-2-ol.
About the authors
M. S. Zavakhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
I. S. Khan
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090
M. O. Barsukova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
A. A. Sapianik
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. G. Samsonenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. N. Dybtsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
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