Synthesis of 5-amino-6-(nitro- NNO -azoxy)-1,2,3,4-tetrazine 1,3-dioxide

M. S. Klenov; N. E. Leonov; A. A. Guskov; A. M. Churakov; Yu. A. Strelenko; V. A. Tartakovsky

doi:10.1007/s11172-019-2628-7

Synthesis of 5-amino-6-(nitro-NNO-azoxy)-1,2,3,4-tetrazine 1,3-dioxide

Authors: Klenov M.S.¹, Leonov N.E.¹^,2, Guskov A.A.¹, Churakov A.M.¹, Strelenko Y.A.¹, Tartakovsky V.A.¹
Affiliations:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2. Mendeleev University of Chemical Technology of Russia
Issue: Vol 68, No 9 (2019)
Pages: 1798-1800
Section: Brief Communications
URL: https://journal-vniispk.ru/1066-5285/article/view/243489
DOI: https://doi.org/10.1007/s11172-019-2628-7
ID: 243489

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Abstract

A reaction of 5-amino-6-(tert-butyl-NNO-azoxy)-1,2,3,4-tetrazine 1,3-dioxide with nitronium tetrafluoroborate affords 5-amino-6-(nitro-NNO-azoxy)-1,2,3,4-tetrazine 1,3-dioxide, which can be of interest as an energetic compound. A plausible mechanism of its formation involves substitutive nitration of the tert-butyl group.