The synthesis of 3,3,3-(Ph2P)3CH-closo-3,1,2-RuC2B9H11, a novel ruthenacarborane complex with a chelate tridentate ligand
- Авторы: Kaltenberg A.A.1, Penkal’ A.M.1, Somov N.V.1, Grishin I.D.1
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Учреждения:
- Lobachevsky State University of Nizhny Novgorod
- Выпуск: Том 68, № 4 (2019)
- Страницы: 770-776
- Раздел: Full Article
- URL: https://journal-vniispk.ru/1066-5285/article/view/243345
- DOI: https://doi.org/10.1007/s11172-019-2484-5
- ID: 243345
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Аннотация
A closo-metallacarborane complex of ruthenium(ii), 3,3,3-(Ph2P)3CH-closo-3,1,2-Ru-C2B9H11, is synthesized and structurally characterized. It is the first example of the metallacarborane clusters with chelate tridentate phosphine ligands. Quantum chemical calculations were carried out to evaluate the possibility of dissociation of one of the Ru-P bonds in this molecule with formation of reactive 16-electron species. According to the cyclic voltammetry study, the complex undergoes irreversible oxidation.
Об авторах
A. Kaltenberg
Lobachevsky State University of Nizhny Novgorod
Email: grishin_i@ichem.unn.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod
A. Penkal’
Lobachevsky State University of Nizhny Novgorod
Email: grishin_i@ichem.unn.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod
N. Somov
Lobachevsky State University of Nizhny Novgorod
Email: grishin_i@ichem.unn.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod
I. Grishin
Lobachevsky State University of Nizhny Novgorod
Автор, ответственный за переписку.
Email: grishin_i@ichem.unn.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod
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