Отправить статью по E-mail Geminal Dicationic Ionothermal Synthesis of One Three-Dimensional Luminescent Strontium(II) Coordination Polymer Based on 1,4-Naphthalenedicarboxylate Acid
- Авторы: Zhu W.J.1, Qin Z.J.1, Bai Y.1, Dang D.B.1
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Учреждения:
- Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
- Выпуск: Том 44, № 7 (2018)
- Страницы: 425-431
- Раздел: Article
- URL: https://journal-vniispk.ru/1070-3284/article/view/214557
- DOI: https://doi.org/10.1134/S1070328418070096
- ID: 214557
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Аннотация
One three-dimensional Sr(II) coordination polymer [C6(MIm)2][Sr3(1,4-NDC)4] (I) (C6(MIm)2 = 1,3-bis(3-methylimidazolium-1-yl)hexyl, 1,4-H2NDC = 1,4-naphthalenedicarboxylate acid) has been synthesized using an ionothermal method and structurally characterized by IR spectroscopy, UV-Vis spectroscopy, XRPD, and X-ray single-crystal structure analysis (СIF file CCDC 1033958). Two types of strontium centers are bridged by two coordination modes of 1,4-H2NDC ligands to form a Sr(II) chain. Each Sr(II) chain is crossconnected to four other chains to generate a 3D coordination polymer, in which C6(MIm)22+ cations as charge balancing species are filled in the channels of the anionic framework. The polymeric solid of I exhibits strong luminescent emission at room temperature.
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Об авторах
W. Zhu
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
Z. Qin
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
Y. Bai
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Автор, ответственный за переписку.
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
D. Dang
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
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