Отправить статью по E-mail Synthesis of 2-(diphenylphosphoryl)phenyl ethers of ethylene glycols and structure of their sodium and potassium complexes
- Авторы: Ivanova I.S.1,2, Polyakova I.N.1, Baulin V.E.2,3, Pyatova E.N.1,2, Krivorot’ko E.S.2, Tsivadze A.Y.2
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Institute of Physiologically Active Compounds
- Выпуск: Том 86, № 4 (2016)
- Страницы: 865-875
- Раздел: Article
- URL: https://journal-vniispk.ru/1070-3632/article/view/214658
- DOI: https://doi.org/10.1134/S1070363216040186
- ID: 214658
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Аннотация
Phase-transfer catalysis and template assembly on sodium and cesium cations were used to prepare 2-(diphenylphosphoryl)phenyl ethers of ethylene glycols Ln with varied number of polyether units (n = 3–8). Previously unknown dinitro and disulfo derivatives of 2-(diphenylphosphoryl)phenyl ethers of di- and triethylene glycols were synthesized. Complexes [NaL4]NCS·C6H6, [NaL4]ClO4, [KL5]NCS, and [KL5]ReO4 were synthesized, and their crystal structure was studied. Structure–stability constant correlations were found for alkali metal complexes with phosphoryl podands Ln and isodentate crown ethers.
Об авторах
I. Ivanova
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Автор, ответственный за переписку.
Email: isivanova@mail.ru
Россия, Leninskii pr. 31, Moscow, 119991; Moscow
I. Polyakova
Kurnakov Institute of General and Inorganic Chemistry
Email: isivanova@mail.ru
Россия, Leninskii pr. 31, Moscow, 119991
V. Baulin
Frumkin Institute of Physical Chemistry and Electrochemistry; Institute of Physiologically Active Compounds
Email: isivanova@mail.ru
Россия, Moscow; Chernogolovka, Moscow oblast
E. Pyatova
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Россия, Leninskii pr. 31, Moscow, 119991; Moscow
E. Krivorot’ko
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Россия, Moscow
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Россия, Moscow
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