Thermal Reactions of Polyfluoro-ortho-chloroarenethiols with Tetrafluoroethylene


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Аннотация

Co-pyrolysis of 2,5-dichloro-3,4,6-trifluorobenzenethiol, 2-chloro-4-trifluoromethyl-3,5,6-trifluorobenzenethiol, and 3-chloro-2,5,6-trifluoropyridine-4-thiol with tetrafluoroethylene has given, heptafluoro-5- chloro-2,3-dihydrobenzo[b]thiophene, 6-trifluoromethylheptafluoro-2,3-dihydrobenzo[b]thiophene, and heptafluoro- 2H,3H-thieno[2,3-c]pyridine, respectively, as the major products. The reactions of these thiols containing the chlorine atom in the ortho-position to the thiol group differ from that between 4-chloro-2,3,5,6- tetrafluorobenzenethiol and tetrafluoroethylene, the latter one giving perfluoroindane as the major product.

Авторлар туралы

P. Nikul’shin

Vorozhtsov Novosibirsk Institute of Organic Chemistry

Email: platonov@nioch.nsc.ru
Ресей, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090

A. Maksimov

Vorozhtsov Novosibirsk Institute of Organic Chemistry

Email: platonov@nioch.nsc.ru
Ресей, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090

Yu. Gatilov

Vorozhtsov Novosibirsk Institute of Organic Chemistry

Email: platonov@nioch.nsc.ru
Ресей, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090

V. Platonov

Vorozhtsov Novosibirsk Institute of Organic Chemistry

Хат алмасуға жауапты Автор.
Email: platonov@nioch.nsc.ru
Ресей, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090

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