Thermal decomposition of anion-exchange resin based on copolymer of 4-vinylpyridine

V. M. Belokhvostov; A. A. Kossoy; D. A. Mukhortov; M. P. Kambur; O. V. Lantratova; E. S. Kurapova; I. A. Blinov

doi:10.1134/S1070427216040054

Thermal decomposition of anion-exchange resin based on copolymer of 4-vinylpyridine

Authors: Belokhvostov V.M.¹, Kossoy A.A.¹, Mukhortov D.A.¹, Kambur M.P.¹, Lantratova O.V.¹, Kurapova E.S.¹, Blinov I.A.¹
Affiliations:
1. FSUE RSC “Applied Chemistry,”
Issue: Vol 89, No 4 (2016)
Pages: 554-558
Section: Inorganic Synthesis and Industrial Inorganic Chemistry
URL: https://journal-vniispk.ru/1070-4272/article/view/213736
DOI: https://doi.org/10.1134/S1070427216040054
ID: 213736

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Abstract

Formal kinetic model is suggested on the basis of experimental studies of the heat-release kinetics in decomposition of an anion-exchange resin, copolymer of N-methyl-4-vinylpyridinium chloride and divinylbenzene. The model makes it possible to determine the service life of the resin in the temperature range 100–170°C in optimization of the process in which monosilane is synthesized from trichlorosilane with the resin used as a catalyst.