Regio- and stereoselective addition of tellurium tetrachloride to methyl propargyl ether

M. V. Musalova; A. G. Khabibulina; M. V. Musalov; V. A. Potapov; S. V. Amosova

doi:10.1134/S1070428017080188

Regio- and stereoselective addition of tellurium tetrachloride to methyl propargyl ether

Authors: Musalova M.V.¹, Khabibulina A.G.¹, Musalov M.V.¹, Potapov V.A.¹, Amosova S.V.¹
Affiliations:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Issue: Vol 53, No 8 (2017)
Pages: 1268-1269
Section: Short Communications
URL: https://journal-vniispk.ru/1070-4280/article/view/216766
DOI: https://doi.org/10.1134/S1070428017080188
ID: 216766

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Abstract

Reaction of tellurium tetrachloride with methyl propargyl ether proceeds regio- and stereoselectively to afford a product of anti-addition against the Markovnikoff’s rule in quantitative yield. The obtained compound was reduced by sodium metabisulfite into E,E-bis(3-methoxy-1-chloroprop-1-en-2-yl)ditellane.