Email this article Alcoholysis of Binor-S with Alcohols under the Action of Ionic Liquid
- Authors: Aminov R.I.1, Khusnutdinov R.I.1
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Affiliations:
- Institute of Petrochemistry and Catalysis
- Issue: Vol 55, No 5 (2019)
- Pages: 587-591
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/220479
- DOI: https://doi.org/10.1134/S1070428019050014
- ID: 220479
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Abstract
Inorganic ionic liquids are first shown to catalyze the alcoholysis of heptacyclo-[8.4.0.02,12.03,8.04,6.05,9.011,13]tetradecane (heptacyclic dimer of norbornadiene, binor-S) with primary and secondary alcohols. The reaction occurs at 65−100°C for 6−14 h via regioselective cleavage of the cyclopropane C4−C5 bond in binor-S to form 10-exo-alkoxyhexacyclo[9.2.1.02,7.03,5.04,8.09,13] tetradecanes in 85−90% yields.
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About the authors
R. I. Aminov
Institute of Petrochemistry and Catalysis
Author for correspondence.
Email: inklab4@gmail.com
Russian Federation, pr. Oktyabrya 141, Ufa, Republic of Bashkortostan, 4500075
R. I. Khusnutdinov
Institute of Petrochemistry and Catalysis
Email: inklab4@gmail.com
Russian Federation, pr. Oktyabrya 141, Ufa, Republic of Bashkortostan, 4500075
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