Synthesis of Polyiodides of N- and S-S-Acetonyl Derivatives of 2,2′-(Disulfanediyl)- and 2,2′-[Alkanediylbis(sulfanyl)]-bisbenzimidazolium


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Abstract

2,2′-(Disulfanediyl)- and 2,2′-[alkanediylbis(sulfanyl)]-bisbenzimidazoles react with aliphatic, aromatic, and heterocyclic α-iodoketones in the presence of elemental iodine without solvents, basic media, and catalysts to afford polyiodides of the N- and S-S-acetonyl derivatives. The selectivity of the alkylation reaction depends on the structure of the starting substrates. In the case of the disulfide, the reaction involves the sulfur atoms to give hitherto unknown disulfanium derivatives. The introduction of an organic bridge between the sulfur atoms leads to the formation of polyiodides of 2,2′-[alkanediylbis(sulfanyl)]bisbenzimidazole N-acetonyl derivatives.

About the authors

L. G. Shagun

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: lara_zhilitskaya@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

I. A. Dorofeev

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: lara_zhilitskaya@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

L. V. Zhilitskaya

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Author for correspondence.
Email: lara_zhilitskaya@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

N. O. Yarosh

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: lara_zhilitskaya@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

L. I. Larina

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: lara_zhilitskaya@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

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