6,6'-[piperazine-1,4-diylbis(methylene)]bis[3,5-di(tert-butyl)-1,2- benzoquinone]: Synthesis and properties
- Авторлар: Sayapin Y.A.1, Tupaeva I.O.2, Tkachev V.V.3, Shilov G.V.3
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Мекемелер:
- Southern Scientific Center of the Russian Academy of Sciences
- Institute of Physical and Organic Chemistry at Southern Federal University
- Institute of Problems of Chemical Physics
- Шығарылым: Том 52, № 2 (2016)
- Беттер: 214-218
- Бөлім: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/213699
- DOI: https://doi.org/10.1134/S1070428016020093
- ID: 213699
Дәйексөз келтіру
Аннотация
Preparation method is developed for a new 6,6'-[piperazine-1,4-diylbis(methylene)]bis[3,5-di(tert-butyl)- 1,2-benzoquinone], including the stage of 3,5-di(tert-butyl)pyrocatechol aminoalkylation by Mannich reaction followed by oxidation. The molecular structure of one of its hydrolysis products, 4,6-di(tert-butyl)-2,3-dihydroxybenzaldehyde, is established by X-ray diffraction (XRD) analysis.
Негізгі сөздер
Авторлар туралы
Yu. Sayapin
Southern Scientific Center of the Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: sayapin@ipoc.rsu.ru
Ресей, ul. Chekhova 41, Rostov-on-Don, 344006
I. Tupaeva
Institute of Physical and Organic Chemistry at Southern Federal University
Email: sayapin@ipoc.rsu.ru
Ресей, Rostov-on-Don
V. Tkachev
Institute of Problems of Chemical Physics
Email: sayapin@ipoc.rsu.ru
Ресей, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
G. Shilov
Institute of Problems of Chemical Physics
Email: sayapin@ipoc.rsu.ru
Ресей, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
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