Reaction of Potassium 1,1,3,3-Tetracyano-2-(2,2-dimethylpropanoyl)propenide with 2-Sulfanylethanol

A. A. Grigor’ev; S. V. Karpov; O. E. Nasakin; V. A. Tafeenko; O. V. Kayukova; Ya. S. Kayukov

doi:10.1134/S107042801803020X

Reaction of Potassium 1,1,3,3-Tetracyano-2-(2,2-dimethylpropanoyl)propenide with 2-Sulfanylethanol

Autores: Grigor’ev A.A.¹, Karpov S.V.¹, Nasakin O.E.¹, Tafeenko V.A.², Kayukova O.V.³, Kayukov Y.S.¹
Afiliações:
1. I.N. Ul’yanov Chuvash State University
2. Faculty of Chemistry
3. Chuvash State Agricultural Academy
Edição: Volume 54, Nº 3 (2018)
Páginas: 503-505
Seção: Short Communications
URL: https://journal-vniispk.ru/1070-4280/article/view/217441
DOI: https://doi.org/10.1134/S107042801803020X
ID: 217441

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The reaction of potassium 2-(2,2-dimethylpropanoyl)-1,1,3,3-tetracyanopropenide with an equimolar amount of 2-sulfanylethanol afforded 2-{5-amino-2-(tert-butyl)-4-cyano-2-[(2-hydroxyethyl)sulfanyl]- 2,3-dihydrofuran-3-ylidene}propanedinitrile, whereas 4-amino-1-(tert-butyl)-1,6-bis[(2-hydroxyethyl)- sulfanyl]-3-imino-1,3-dihydrofuro[3,4-c]pyridine-7-carbonitrile was obtained in the reaction with excess 2-sulfanylethanol.