Enviar artigo por via de e-mail Acidic Zeolite-Catalyzed Reaction of 2,4-Diaryl-1,1,1-trifluorobut-3-yn-2-ols with Benzene. A New Synthesis of 1,3-Diaryl-1-trifluoromethylindenes
- Autores: Nursahedova S.K.1, Zerov A.V.2, Vasilyev A.V.1,2
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Afiliações:
- St. Petersburg State Forest Technical University
- St. Petersburg State University
- Edição: Volume 54, Nº 12 (2018)
- Páginas: 1764-1771
- Seção: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/219490
- DOI: https://doi.org/10.1134/S1070428018120047
- ID: 219490
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Resumo
Reactions of 2,4-diaryl-1,1,1-trifluorobut-3-yn-2-ols with benzene in the presence of HUSY acidic zeolite (CBV-720) at 100°C in 1 h (glass high-pressure reactor) led to the formation of 1,3-diaryl-1-trifluoromethylindenes in 39–92% yield. A probable reaction mechanism was proposed, which involves formation of the corresponding trifluoromethyl-substituted propargyl cations.
Sobre autores
S. Nursahedova
St. Petersburg State Forest Technical University
Email: aleksvasil@mail.ru
Rússia, Institutskii per. 5, St. Petersburg, 194021
A. Zerov
St. Petersburg State University
Email: aleksvasil@mail.ru
Rússia, Universitetskii pr. 26, St. Petersburg, 198504
A. Vasilyev
St. Petersburg State Forest Technical University; St. Petersburg State University
Autor responsável pela correspondência
Email: aleksvasil@mail.ru
Rússia, Institutskii per. 5, St. Petersburg, 194021; Universitetskii pr. 26, St. Petersburg, 198504
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