Reactions of γ-sultones containing a polycyclic fragment

Аннотация

Hydrolytic cleavage of cage γ-sultones have been studied. Alkaline hydrolysis of homoadamantane γ-sultone leads to the formation of sulfonates with erythro configuration. The reduction of homoadamantane γ-sultone with LiAlH₄–AlCl₃ yields desulfurization and deoxygenation products.