Synthesis of polyfunctional 2-thionicotinonitriles

I. N. Bardasov; D. L. Mikhailov; M. Yu. Belikov; A. Yu. Alekseeva; O. V. Ershov

doi:10.1134/S1070428016110087

Synthesis of polyfunctional 2-thionicotinonitriles

作者: Bardasov I.N.¹, Mikhailov D.L.¹, Belikov M.Y.¹, Alekseeva A.Y.¹, Ershov O.V.¹
隶属关系:
1. I.N. Ul’yanov Chuvash State University
期: 卷 52, 编号 11 (2016)
页面: 1600-1602
栏目: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/215202
DOI: https://doi.org/10.1134/S1070428016110087
ID: 215202

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Reaction of 2-amino-4-arylbuta-1,3-diene-1,1,3-tricarbonitriles with sulfur in benzonitrile affords 4-amino-6-aryl-2-thio-1,2-dihydropyridine-3,5-dicarbonitriles. They also are synthesized by an authentic synthesis from 4-amino-6-aryl-2-bromopyridine-3,5-dicarbonitriles and sodium hydrosulfide.