Stereoselective addition of tellurium tetrachloride to 4-octyne

M. V. Musalova; M. V. Musalov; V. A. Potapov; S. B. Amosova

doi:10.1134/S1070428017020282

Stereoselective addition of tellurium tetrachloride to 4-octyne

作者: Musalova M.V.¹, Musalov M.V.¹, Potapov V.A.¹, Amosova S.B.¹
隶属关系:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
期: 卷 53, 编号 2 (2017)
页面: 301-302
栏目: Short Communications
URL: https://journal-vniispk.ru/1070-4280/article/view/215854
DOI: https://doi.org/10.1134/S1070428017020282
ID: 215854

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Reaction of tellurium tetrachloride with 4-octyne occurs as an anti-addition and leads to the formation of trichloro[(Е)-1-propyl-2-chloropent-1-enyl]tellane which was reduced sodium metabisulfite in a two-phase system C₆Н₆–H₂O affording bis[(Е)-1-propyl-2-chloropent-1-enyl]ditellane.