Formylation of indol-1-yl acetates

Zh. V. Chirkova; F. A. Chernov; S. I. Filimonov; I. G. Abramov; V. V. Plakhtinskii; A. S. Danilova

doi:10.1134/S1070428017110069

Formylation of indol-1-yl acetates

作者: Chirkova Z.V.¹, Chernov F.A.¹, Filimonov S.I.¹, Abramov I.G.¹, Plakhtinskii V.V.¹, Danilova A.S.¹
隶属关系:
1. Yaroslavl State Technical University
期: 卷 53, 编号 11 (2017)
页面: 1655-1659
栏目: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/216908
DOI: https://doi.org/10.1134/S1070428017110069
ID: 216908

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Preparation procedure was developed for 3-formylindole-5,6-dicarbonitriles underlain by the treatment of 1-acetoxyindole-5,6-dicarbonitriles with Vilsmeier-Haack reagent; a special feature of this reaction consisted in a replacement of the OAc group for hydrogen. A probable mechanism was assumed of the formation of 3-formylindole-5,6-dicarbonitriles.